Iridium (Ir)
Element 77 · transition metal · group 9, period 6
Iridium is element 77, a transition metal in group 9 and period 6. Its electron configuration is [Xe] 4f14 5d7 6s2. The shells fill 2, 8, 18, 32, 15, 2. Courses differ here. Counting only the outer s subshell gives 2; counting the inner d subshell with it gives 9, which is the group number. It commonly forms ions with a charge of +4, +3.
- 77 protons
- 2/9 valence e−
- +4, +3
- d-block
Properties
| Atomic number | 77 |
|---|---|
| Symbol | Ir |
| Standard atomic weight | 192.22 u |
| Group | 9 |
| Period | 6 |
| Block | d-block |
| Category | transition metal |
| Electron configuration | 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d7 6s2 |
| Noble-gas notation | [Xe] 4f14 5d7 6s2 |
| Electrons per shell | 2, 8, 18, 32, 15, 2 |
| Valence electrons | 2 or 9 |
| Common ionic charge | +4, +3 |
| Electronegativity (Pauling) | 2.2 |
| Protons / electrons | 77 / 77 |
Electron configuration of iridium
Orbitals fill from the lowest energy upward. Writing that out for iridium gives 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d7 6s2, which is 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d7 6s2 in plain text.
Everything up to Xe is the same as in that noble gas, so it is usually abbreviated to [Xe] 4f14 5d7 6s2. The part outside the bracket is what does the chemistry.
| Subshell | Electrons | Capacity |
|---|---|---|
| 1s | 2 | 2 |
| 2s | 2 | 2 |
| 2p | 6 | 6 |
| 3s | 2 | 2 |
| 3p | 6 | 6 |
| 3d | 10 | 10 |
| 4s | 2 | 2 |
| 4p | 6 | 6 |
| 4d | 10 | 10 |
| 4f | 14 | 14 |
| 5s | 2 | 2 |
| 5p | 6 | 6 |
| 5d | 7 | 10 |
| 6s | 2 | 2 |
Iridium ion charge
Iridium commonly forms ions with a charge of +4, +3.
Common questions
How many valence electrons does iridium have?
There is no single agreed answer for iridium. Courses differ here. Counting only the outer s subshell gives 2; counting the inner d subshell with it gives 9, which is the group number. Check which convention your course uses before answering.
What is the electron configuration of iridium?
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d7 6s2, or [Xe] 4f14 5d7 6s2 written from the previous noble gas. Orbitals fill lowest energy first.
What is the charge of iridium?
Iridium commonly forms ions with a charge of +4, +3. Transition metals have several accessible oxidation states, which is why more than one charge is listed.
How many protons, electrons and neutrons does iridium have?
A neutral iridium atom has 77 protons and 77 electrons. Its standard atomic weight is 192.22, so the most common isotope has about 115 neutrons.
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