Neptunium (Np)
Element 93 · actinide · group 3, period 7
Neptunium is element 93, a actinide in group 3 and period 7. Its electron configuration is [Rn] 5f4 6d1 7s2. The shells fill 2, 8, 18, 32, 22, 9, 2. The f-block elements draw on three subshells, so a single valence count is not meaningful for them. It commonly forms ions with a charge of +3.
- 93 protons
- 2/3 valence e−
- +3
- f-block
Properties
| Atomic number | 93 |
|---|---|
| Symbol | Np |
| Standard atomic weight | 237 u |
| Group | 3 |
| Period | 7 |
| Block | f-block |
| Category | actinide |
| Electron configuration | 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 5f4 6s2 6p6 6d1 7s2 |
| Noble-gas notation | [Rn] 5f4 6d1 7s2 |
| Electrons per shell | 2, 8, 18, 32, 22, 9, 2 |
| Valence electrons | 2 or 3 |
| Common ionic charge | +3 |
| Electronegativity (Pauling) | 1.36 |
| Protons / electrons | 93 / 93 |
Electron configuration of neptunium
Orbitals fill from the lowest energy upward. Writing that out for neptunium gives 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 5f4 6s2 6p6 6d1 7s2, which is 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 5f4 6s2 6p6 6d1 7s2 in plain text.
Everything up to Rn is the same as in that noble gas, so it is usually abbreviated to [Rn] 5f4 6d1 7s2. The part outside the bracket is what does the chemistry.
| Subshell | Electrons | Capacity |
|---|---|---|
| 1s | 2 | 2 |
| 2s | 2 | 2 |
| 2p | 6 | 6 |
| 3s | 2 | 2 |
| 3p | 6 | 6 |
| 3d | 10 | 10 |
| 4s | 2 | 2 |
| 4p | 6 | 6 |
| 4d | 10 | 10 |
| 4f | 14 | 14 |
| 5s | 2 | 2 |
| 5p | 6 | 6 |
| 5d | 10 | 10 |
| 5f | 4 | 14 |
| 6s | 2 | 2 |
| 6p | 6 | 6 |
| 6d | 1 | 10 |
| 7s | 2 | 2 |
Neptunium ion charge
Neptunium commonly forms ions with a charge of +3.
Common questions
How many valence electrons does neptunium have?
There is no single agreed answer for neptunium. The f-block elements draw on three subshells, so a single valence count is not meaningful for them. Check which convention your course uses before answering.
What is the electron configuration of neptunium?
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 5f4 6s2 6p6 6d1 7s2, or [Rn] 5f4 6d1 7s2 written from the previous noble gas. Orbitals fill lowest energy first.
What is the charge of neptunium?
Neptunium commonly forms ions with a charge of +3. Transition metals have several accessible oxidation states, which is why more than one charge is listed.
How many protons, electrons and neutrons does neptunium have?
A neutral neptunium atom has 93 protons and 93 electrons. Its standard atomic weight is 237, so the most common isotope has about 144 neutrons.
Nearby elements
See the ionic charge of every element →