Samarium (Sm)

Element 62 · lanthanide · group 3, period 6

Electron shells, 2 + 8 + 18 + 24 + 8 + 2. The outer shell is highlighted - it is the only one that takes part in bonding.

Samarium is element 62, a lanthanide in group 3 and period 6. Its electron configuration is [Xe] 4f6 6s2. The shells fill 2, 8, 18, 24, 8, 2. The f-block elements draw on three subshells, so a single valence count is not meaningful for them. It commonly forms ions with a charge of +3.

62 protons
2/2 valence e−
+3
f-block

Properties

Atomic number	62
Symbol	Sm
Standard atomic weight	150.36 u
Group	3
Period	6
Block	f-block
Category	lanthanide
Electron configuration	1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f⁶ 5s² 5p⁶ 6s²
Noble-gas notation	[Xe] 4f⁶ 6s²
Electrons per shell	2, 8, 18, 24, 8, 2
Valence electrons	2 or 2
Common ionic charge	+3
Electronegativity (Pauling)	1.17
Protons / electrons	62 / 62

Electron configuration of samarium

Orbitals fill from the lowest energy upward. Writing that out for samarium gives 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f⁶ 5s² 5p⁶ 6s², which is 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f6 5s2 5p6 6s2 in plain text.

Everything up to Xe is the same as in that noble gas, so it is usually abbreviated to [Xe] 4f⁶ 6s². The part outside the bracket is what does the chemistry.

Subshell	Electrons	Capacity
1s	2	2
2s	2	2
2p	6	6
3s	2	2
3p	6	6
3d	10	10
4s	2	2
4p	6	6
4d	10	10
4f	6	14
5s	2	2
5p	6	6
6s	2	2

Samarium ion charge

Samarium commonly forms ions with a charge of +3.

Common questions

How many valence electrons does samarium have?

There is no single agreed answer for samarium. The f-block elements draw on three subshells, so a single valence count is not meaningful for them. Check which convention your course uses before answering.

What is the electron configuration of samarium?

1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f6 5s2 5p6 6s2, or [Xe] 4f6 6s2 written from the previous noble gas. Orbitals fill lowest energy first.

What is the charge of samarium?

Samarium commonly forms ions with a charge of +3. Transition metals have several accessible oxidation states, which is why more than one charge is listed.

How many protons, electrons and neutrons does samarium have?

A neutral samarium atom has 62 protons and 62 electrons. Its standard atomic weight is 150.36, so the most common isotope has about 88 neutrons.

See the ionic charge of every element →

How this page was produced. The configuration was built by filling orbitals in energy order from atomic number 62 alone, not looked up. The shell counts, the valence count and the charge all follow from it. Nothing on this page is written per element.