chemcheat

Bismuth (Bi)

Element 83 · post-transition metal · group 15, period 6

Bismuth shell diagram: 2, 8, 18, 32, 18, 5 electronsBi83
Electron shells, 2 + 8 + 18 + 32 + 18 + 5. The outer shell is highlighted - it is the only one that takes part in bonding.

Bismuth is element 83, a post-transition metal in group 15 and period 6. Its electron configuration is [Xe] 4f14 5d10 6s2 6p3. That leaves 5 valence electrons in the outer shell, with the shells filling 2, 8, 18, 32, 18, 5. It is 3 electrons short of a full octet, so it gains them and carries a charge of +3.

Properties

Atomic number83
SymbolBi
Standard atomic weight208.98 u
Group15
Period6
Blockp-block
Categorypost-transition metal
Electron configuration1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p3
Noble-gas notation[Xe] 4f14 5d10 6s2 6p3
Electrons per shell2, 8, 18, 32, 18, 5
Valence electrons5
Common ionic charge+3
Electronegativity (Pauling)2.02
Protons / electrons83 / 83

Electron configuration of bismuth

Orbitals fill from the lowest energy upward. Writing that out for bismuth gives 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p3, which is 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p3 in plain text.

Everything up to Xe is the same as in that noble gas, so it is usually abbreviated to [Xe] 4f14 5d10 6s2 6p3. The part outside the bracket is what does the chemistry.

SubshellElectronsCapacity
1s 2 2
2s 2 2
2p 6 6
3s 2 2
3p 6 6
3d 10 10
4s 2 2
4p 6 6
4d 10 10
4f 14 14
5s 2 2
5p 6 6
5d 10 10
6s 2 2
6p 3 6

Bismuth ion charge

Bismuth commonly forms ions with a charge of +3.

It has 5 valence electrons, so it is 3 short of a full octet and 5 above an empty outer shell. An atom takes whichever route is shorter, which is why the charge comes out as it does.

Common questions

How many valence electrons does bismuth have?

Bismuth has 5 valence electrons. For a main-group element the count is the group number minus 10, and bismuth is in group 15.

What is the electron configuration of bismuth?

1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p3, or [Xe] 4f14 5d10 6s2 6p3 written from the previous noble gas. Orbitals fill lowest energy first.

What is the charge of bismuth?

Bismuth commonly forms ions with a charge of +3. With 5 valence electrons it is 3 short of an octet and 5 above an empty shell, so it takes whichever route is shorter.

How many protons, electrons and neutrons does bismuth have?

A neutral bismuth atom has 83 protons and 83 electrons. Its standard atomic weight is 208.98, so the most common isotope has about 126 neutrons.

See the ionic charge of every element →

How this page was produced. The configuration was built by filling orbitals in energy order from atomic number 83 alone, not looked up. The shell counts, the valence count and the charge all follow from it. Nothing on this page is written per element.