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Polonium (Po)

Element 84 · reactive nonmetal · group 16, period 6

Polonium shell diagram: 2, 8, 18, 32, 18, 6 electronsPo84
Electron shells, 2 + 8 + 18 + 32 + 18 + 6. The outer shell is highlighted - it is the only one that takes part in bonding.

Polonium is element 84, a reactive nonmetal in group 16 and period 6. Its electron configuration is [Xe] 4f14 5d10 6s2 6p4. That leaves 6 valence electrons in the outer shell, with the shells filling 2, 8, 18, 32, 18, 6. It is 2 electrons short of a full octet, so it gains them and carries a charge of +4, +2.

Properties

Atomic number84
SymbolPo
Standard atomic weight209 u
Group16
Period6
Blockp-block
Categoryreactive nonmetal
Electron configuration1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p4
Noble-gas notation[Xe] 4f14 5d10 6s2 6p4
Electrons per shell2, 8, 18, 32, 18, 6
Valence electrons6
Common ionic charge+4, +2
Electronegativity (Pauling)2
Protons / electrons84 / 84

Electron configuration of polonium

Orbitals fill from the lowest energy upward. Writing that out for polonium gives 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p4, which is 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p4 in plain text.

Everything up to Xe is the same as in that noble gas, so it is usually abbreviated to [Xe] 4f14 5d10 6s2 6p4. The part outside the bracket is what does the chemistry.

SubshellElectronsCapacity
1s 2 2
2s 2 2
2p 6 6
3s 2 2
3p 6 6
3d 10 10
4s 2 2
4p 6 6
4d 10 10
4f 14 14
5s 2 2
5p 6 6
5d 10 10
6s 2 2
6p 4 6

Polonium ion charge

Polonium commonly forms ions with a charge of +4, +2.

It has 6 valence electrons, so it is 2 short of a full octet and 6 above an empty outer shell. An atom takes whichever route is shorter, which is why the charge comes out as it does.

Common questions

How many valence electrons does polonium have?

Polonium has 6 valence electrons. For a main-group element the count is the group number minus 10, and polonium is in group 16.

What is the electron configuration of polonium?

1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p4, or [Xe] 4f14 5d10 6s2 6p4 written from the previous noble gas. Orbitals fill lowest energy first.

What is the charge of polonium?

Polonium commonly forms ions with a charge of +4, +2. With 6 valence electrons it is 2 short of an octet and 6 above an empty shell, so it takes whichever route is shorter.

How many protons, electrons and neutrons does polonium have?

A neutral polonium atom has 84 protons and 84 electrons. Its standard atomic weight is 209, so the most common isotope has about 125 neutrons.

See the ionic charge of every element →

How this page was produced. The configuration was built by filling orbitals in energy order from atomic number 84 alone, not looked up. The shell counts, the valence count and the charge all follow from it. Nothing on this page is written per element.